- VN Monaca, 1. slobodni trening, 22. 05. 2014.
- VN Monaca, 2. slobodni trening, 22. 05. 2014.
- VN Monaca, 3. slobodni trening, 24. 05. 2014.
- VN Monaca, kvalifikacije, 24. 05. 2014.
| Poz | Br | Vozač | Momčad | Q1 | Q2 | Q3 | Krugova |
| 1 | 6 | Nico Rosberg | Mercedes | 1:17.678 | 1:16.465 | 1:15.989 | 26 |
| 2 | 44 | Lewis Hamilton | Mercedes | 1:17.823 | 1:16.354 | 1:16.048 | 27 |
| 3 | 3 | Daniel Ricciardo | Red Bull Racing Renault | 1:17.900 | 1:17.233 | 1:16.384 | 22 |
| 4 | 1 | Sebastian Vettel | Red Bull Racing Renault | 1:18.383 | 1:17.074 | 1:16.547 | 25 |
| 5 | 14 | Fernando Alonso | Ferrari | 1:17.853 | 1:17.200 | 1:16.686 | 27 |
| 6 | 7 | Kimi Räikkönen | Ferrari | 1:17.902 | 1:17.398 | 1:17.389 | 27 |
| 7 | 25 | Jean-Eric Vergne | Toro Rosso Renault | 1:17.557 | 1:17.657 | 1:17.540 | 26 |
| 8 | 20 | Kevin Magnussen | McLaren Mercedes | 1:17.978 | 1:17.609 | 1:17.555 | 25 |
| 9 | 26 | Daniil Kvyat | Toro Rosso Renault | 1:18.616 | 1:17.594 | 1:18.090 | 23 |
| 10 | 11 | Sergio Perez | Force India Mercedes | 1:18.108 | 1:17.755 | 1:18.327 | 26 |
| 11 | 27 | Nico Hulkenberg | Force India Mercedes | 1:18.432 | 1:17.846 | 20 | |
| 12 | 22 | Jenson Button | McLaren Mercedes | 1:17.890 | 1:17.988 | 20 | |
| 13 | 77 | Valtteri Bottas | Williams Mercedes | 1:18.407 | 1:18.082 | 20 | |
| 14 | 8 | Romain Grosjean | Lotus Renault | 1:18.335 | 1:18.196 | 23 | |
| 15 | 13 | Pastor Maldonado | Lotus Renault | 1:18.585 | 1:18.356 | 21 | |
| 16 | 19 | Felipe Massa | Williams Mercedes | 1:18.209 | 10 | ||
| 17 | 21 | Esteban Gutierrez | Sauber Ferrari | 1:18.741 | 11 | ||
| 18 | 99 | Adrian Sutil | Sauber Ferrari | 1:18.745 | 11 | ||
| 19 | 17 | Jules Bianchi | Marussia Ferrari | 1:19.332 | 10 | ||
| 20 | 4 | Max Chilton | Marussia Ferrari | 1:19.928 | 9 | ||
| 21 | 10 | Kamui Kobayashi | Caterham Renault | 1:20.133 | 9 | ||
| 22 | 9 | Marcus Ericsson | Caterham Renault | 1:21.732 | 9 | ||
| Q1 107% vrijeme | 1:22.985 |
